Convective dispersion without molecular diffusion

DOI10.1016/S0378-4371(03)00027-XMaRDI QIDQ1866930zbMATH OpenFDO

Authors Kevin D. Dorfman, Howard Brenner

Publication date 23 April 2003

Published in Physica A (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/cond-mat/0301125

zbMATH Keywords

first-order kineticsinstantaneous state-specific particle velocitytwo-state particle

Mathematics Subject Classification ID

Diffusion (76R50) Transport processes in time-dependent statistical mechanics (82C70)

Abstract: A method-of-moments scheme is invoked to compute the asymptotic, long-time mean (or composite) velocity and dispersivity (effective diffusivity) of a two-state particle undergoing one-dimensional convective-diffusive motion accompanied by a reversible linear transition (``chemical reaction or ``change in phase) between these states. The instantaneous state-specific particle velocity is assumed to depend only upon the instantaneous state of the particle, and the transition between states is assumed to be governed by spatially-independent, first-order kinetics. Remarkably, even in the absence of molecular diffusion, the average transport of the ``composite particle exhibits gaussian diffusive behavior in the long-time limit, owing to the effectively stochastic nature of the overall transport phenomena induced by the interstate transition. The asymptotic results obtained are compared with numerical computations.

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Cites work

• Dispersion of chemical solutes in chromatographs and reactors
• On the dispersion of a solute by diffusion, convection and exchange between phases
• Stochastic approach to chemical kinetics

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(4)

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