Transition metal-free approach for late-stage benzylic C(sp3)–H etherifications and esterifications
Description of the dataset: Origin of the data: Experimental spectroscopic measurements Data Type: experimental measurements, open access supporting information The data are in CSV, XLSX and FBSW. Supporting information are supplied in PDF format. Data generated by instruments: Varian Cary 5000 UV-Vis-NIR spectrophotometer for UV-Vis measurements, Varian Cary Eclipse fluorescence spectrophotomer for fluorescence quenching measurements. Analytical and procedural information: Stern-Volmer fluorescence quenching experiments and UV-Vis measurements. Definition of variables: Wavelength, Absorbance, Concentration Units of measurement: nanometers (nm), moles-per-litre (mol/l) Abbreviations: File names and data headers use the following abbreviations: SVQuench refers to Stern-Volmer quenching experiments MesAcrMe xx refers to data related to the catalyst 9-mesityl-10-methylacridinium. Xx is the amount of catalyst in mol/l (10-4 should be intended as 0.1 mmol/l and so on). EtAn xx refer to measurements related to 8-ethylanisol. Xx is the amount of quencher in mol/l as above. BenzAc xx refer to measurements related to benzoic acid. Xx is the amount of quencher in mol/l as above. Pyrz xx refer to measurements related to pyrazole. Xx is the amount of quencher in mol/l as above.
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