Transition metal-free approach for late-stage benzylic C(sp3)–H etherifications and esterifications
DOI10.5281/zenodo.7684265Zenodo7684265MaRDI QIDQ6708873FDOQ6708873
Dataset published at Zenodo repository.
Robin Cauwenbergh, Yu Zhang, Gandhi Sivaraman, Andrea Guidetti, Shoubhik Das, Philippe Nimmegeers, Steven Van Passel, Prakash Kumar Sahoo, Yuman Qin, Peng Ren
Publication date: 28 February 2023
Copyright license: Creative Commons Attribution 4.0 International
Description of the dataset: Origin of the data: Experimental spectroscopic measurements Data Type: experimental measurements, open access supporting information The data are in CSV, XLSX and FBSW. Supporting information are supplied in PDF format. Data generated by instruments: Varian Cary 5000 UV-Vis-NIR spectrophotometer for UV-Vis measurements, Varian Cary Eclipse fluorescence spectrophotomer for fluorescence quenching measurements. Analytical and procedural information: Stern-Volmer fluorescence quenching experiments and UV-Vis measurements. Definition of variables: Wavelength, Absorbance, Concentration Units of measurement: nanometers (nm), moles-per-litre (mol/l) Abbreviations: File names and data headers use the following abbreviations: SVQuench refers to Stern-Volmer quenching experiments MesAcrMe xx refers to data related to the catalyst 9-mesityl-10-methylacridinium. Xx is the amount of catalyst in mol/l (10-4 should be intended as 0.1 mmol/l and so on). EtAn xx refer to measurements related to 8-ethylanisol. Xx is the amount of quencher in mol/l as above. BenzAc xx refer to measurements related to benzoic acid. Xx is the amount of quencher in mol/l as above. Pyrz xx refer to measurements related to pyrazole. Xx is the amount of quencher in mol/l as above.
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