Data and processing scripts for: Towards detection of molecular parity violation via chiral co-sensing: the $^1$H/$^{31}$P model system
DOI10.5281/zenodo.14802698Zenodo14802698MaRDI QIDQ6711143FDOQ6711143
Dataset published at Zenodo repository.
John Blanchard, Danila Barskiy, Andres Emilio Wedenig, Denis Kargin, Konstantin Joachim Gaul, Rudolf Pietschnig, Dr. Manfred Wagner, Dmitry Budker, James Eills, Kirill Sheberstov, Robert Berger, Erik van Dyke
Publication date: 4 February 2025
Copyright license: Creative Commons Attribution 4.0 International
Abstract: "Fundamental weak interactions have been shown to violate parity in both nuclear and atomic systems. However, observation of parity violation in a molecular system has proven an elusive target. Nuclear spin dependent contributions of the weak interaction are expected to result in energetic differences between enantiomers manifesting in nuclear magnetic resonance (NMR) spectra as chemical shift differences on the order of parts-per-trillion to parts-per-billion ($\mu$Hz to mHz) for high-$Z$ nuclei. This method seeks to use simultaneous measurements of the diastereomeric splittings for a light and a heavy nucleus in solution-state NMR to resolve chemical shift differences persisting in a non-chiral environment between enantiomers of chiral compounds smaller than the typical high-field NMR linewidth. Sources of error must be identified and minimized to verify that the observed effect is, in fact, due to parity violation and not systematic effects. This paper presents a detailed analysis of a system incorporating $^{31}$P and $^{1}$H NMR to elucidate the systematic effects and to guide experiments with higher-$Z$ nuclei where molecular parity violation may be resolved." This repository entry contains the raw data and python script used to process the data presented in the main text as well as part of the supplementary information.
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