Determination of the zeta potential for highly charged colloidal suspensions

DOI10.1098/RSTA.2011.0024MaRDI QIDQ3095559zbMATH OpenOpenAlexWikidataFDO

Authors G. Giupponi, I. Pagonabarraga

Publication date 3 November 2011

Published in Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1102.4918

zbMATH Keywords

electrophoresiselectrostatic radiuslattice Boltzmann methodmesoscopic modelszeta potential

Mathematics Subject Classification ID

Suspensions (76T20)

Abstract: We compute the electrostatic potential at the surface, or zeta potential $zeta$, of a charged particle embedded in a colloidal suspension using a hybrid mesoscopic model. We show that for weakly perturbing electric fields, the value of $zeta$ obtained at steady state during electrophoresis is statistically indistinguishable from $zeta$ in thermodynamic equilibrium. We quantify the effect of counterions concentration on $zeta$. We also evaluate the relevance of the lattice resolution for the calculation of $zeta$ and discuss how to identify the effective electrostatic radius.

Recommendations

• The \(\text{TiO}_2\)-electrolyte solution interface: Calculation of \(\zeta\) potential using non-equilibrium theories
• Electrophoretic properties of charged colloidal suspensions: application of a hybrid MD/LB method
• Ion steric effects on electrophoresis of a colloidal particle
• Electrohydrodynamics of suspensions structure.
• Sur l'électrophorèse d'un ensemble de particules portant la même densité uniforme de charges

Cites work

• Numerical simulations of particulate suspensions via a discretized Boltzmann equation. Part 1. Theoretical foundation

Cited in

(5)

• The \(\text{TiO}_2\)-electrolyte solution interface: Calculation of \(\zeta\) potential using non-equilibrium theories
• Non-equilibrium electrosurface phenomena: A case of biological interest
• Correlations between the maximum parameters of DLVO interaction energy curves and the electrolyte concentration
• Ion steric effects on electrophoresis of a colloidal particle
• Kinetics of charge inversion

This page was built for publication: Determination of the zeta potential for highly charged colloidal suspensions

Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q3095559)