Effects of confinement for single-well potentials
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Asymptotic expansions of solutions to ordinary differential equations (34E05) Particular ordinary differential operators (Dirac, one-dimensional Schrödinger, etc.) (34L40) Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Selfadjoint operator theory in quantum theory, including spectral analysis (81Q10) Semiclassical techniques, including WKB and Maslov methods applied to problems in quantum theory (81Q20)
Abstract: We study bound states generated by a unique potential minimum in the situation where the system is strongly confined to a bounded region containing the minimum (by imposing Dirichlet boundary conditions). In this case the eigenvalues of the confined system differ from those of the unconfined system by an exponentially small quantity in the semiclassical limit. An asymptotic expansion for this shift is established. The formulas are evaluated explicitly for the harmonic oscillator and an application to the Coulomb potential at a fixed angular momentum is given.
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Cites work
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- scientific article; zbMATH DE number 3079370 (Why is no real title available?)
- Multiple wells in the semi-classical limit I
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Cited in
(9)- Finite volume effects in self-coupled geometries
- Exponentially confining potential well
- Zero-point energies of subharmonic oscillators
- Einstein coefficients and dipole moments for the asymmetrically confined harmonic oscillator
- Spectral characteristics for a spherically confined -a/r+br^2 potential
- Confined Lennard-Jones potential: a variational treatment
- On the energies of a bounded Coulomb potential
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