Entropy balance in distributed reversible Gray-Scott model

DOI10.1016/J.PHYSD.2010.02.001MaRDI QIDQ972246zbMATH OpenOpenAlexFDO

Authors Hitoshi Mahara, Tomohiko Yamaguchi

Publication date 25 May 2010

Published in Physica D (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1016/j.physd.2010.02.001

zbMATH Keywords

entropy balanceentropy changeentropy flowentropy productionmulti-stabilityreaction-diffusion systemreversible Gray-Scott model

Mathematics Subject Classification ID

Reaction-diffusion equations (35K57) Thermodynamic formalism, variational principles, equilibrium states for dynamical systems (37D35) Strange attractors, chaotic dynamics of systems with hyperbolic behavior (37D45)

Review text

A practical way to calculate the entropy change in the distributed media composed of reversible Gray-Scott model is demonstrated. The entropy change is given as the sum of the entropy production and the divergence of entropy flow. The divergence of entropy is calculated based on the chemical potential of steady state. It becomes evident that: (i) the entropy change for the emergence of dissipative structures in the open system can be positive or negative, (ii) most of the entropy produced inside the system is thrown out to the environment when dissipative structures are developing, (iii) the entropy production and the divergence of entropy flow balance completely, when the system shows static steady states, (iv) the entropy change behaves as if it is the time derivative of the entropy production. Prior to these calculations of entropy balance, the features of emergent patterns in the two-dimensional system are examined in terms of entropy production solely. The results imply that the entropy production can be an index for us to discriminate spatial patterns, but is not a global thermodynamic potential for the evolution of dissipative structures.

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Cites work

• Entropy production in a two-dimensional reversible Gray-Scott system
• scientific article; zbMATH DE number 3566657 (Why is no real title available?)
• scientific article; zbMATH DE number 1161490 (Why is no real title available?)
• Spiral waves in the Belousov-Zhabotinskii reaction
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Cited in

(3)

• Reversible Gray-Scott model as a tool of thermodynamic investigation in non-equilibrium chemical systems
• Shannon entropy: a rigorous notion at the crossroads between probability, information theory, dynamical systems and statistical physics
• Calculation of the entropy balance equation in a non-equilibrium reaction-diffusion system

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