quantum Hamiltonian (non-rigid rotor)

Community: MathModDB

mathematical expression

Available identifiers

MaRDI QIDQ6674478

quantum-mechanical represention of a molecule as a non-rigid rotor, named after William Rowan Hamilton

Defining Formula: $\hat{H}=B{\hat{J}}^2+D{\hat{J}}^4$

$B$ represents rotational constant

$D$ represents centrifugal distortion constant

$H$ represents Hamiltonian operator

$J$ represents angular momentum operator

Mathematical expressions specializing quantum Hamiltonian (non-rigid rotor)

quantum Hamiltonian (linear rotor)

Related URL

https://en.wikipedia.org/wiki/Rigid_rotor
https://en.wikipedia.org/wiki/Rotational_spectroscopy
https://www.wikidata.org/wiki/Q2915184

Further items linking to quantum Hamiltonian (non-rigid rotor)

Item	Property
linear rotor (non-rigid)	contains

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