Quantum eigen energy (anharmonic)

eigenenergies of anharmonic oscillator systems.

formula

Description

Eigenenergies of anharmonic oscillator systems, e.g. molecular vibrations, beyond the harmonic approximation.

Formula(s) and Quantities

$E_{n} = \sum_{r = 1}^{3 N - 6} ω_{r} (n_{r} + \frac{1}{2}) + \sum_{r > s} χ_{r s} (n_{r} + \frac{1}{2}) (n_{s} + \frac{1}{2})$
$E$ represents quantum eigen energy
$N$ represents number of particles
$χ$ represents anharmonicity constant
$ω$ represents vibration frequency (harmonic)
$n$ represents quantum number

Specializations

quantum eigen energy (harmonic)

Further links

Item	Property
normal mode (anharmonic)	contains

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