normal coordinate (Q6674076)

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pattern of motion in which all parts of the system move sinusoidally with the same frequency and with a fixed phase relation
  • Normal Mode Coordinate
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    normal coordinate
    pattern of motion in which all parts of the system move sinusoidally with the same frequency and with a fixed phase relation
    • Normal Mode Coordinate

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    Normal coordinates refer to the positions of atoms away from their equilibrium positions, wrt a normal mode of vibration. Formally, normal modes are determined by solving a secular determinant, and then the normal coordinates can be expressed as a summation over the cartesian coordinates (over the atom positions). The normal modes diagonalize the matrix governing the molecular vibrations.
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