Linear parameter estimation (Fowler-Guggenheim isotherm model)

linear estimation of Fowler–Guggenheim parameters

computational task, linear task

MaRDI QIDQ6820964FDOCommunityMathModDB

Named after

Ralph H. Fowler, Edward A. Guggenheim

Description

This task estimates the Fowler–Guggenheim equilibrium constant and the interaction energy using the linearized form of the isotherm. Experimental equilibrium data are transformed and fitted using linear regression, providing a simplified estimation method. While computationally efficient, this approach may introduce bias from linearization. The results characterize the adsorption affinity and the sign and magnitude of lateral adsorption interactions.

Contained entities

linear Fowler-Guggenheim equation	$\ln (\frac{C_e(1-\theta )}{\theta })=-\ln (K_{FG})+\frac{2\theta W}{RT}$
	$C_e$ represents solute concentration (equilibrium)
	$\theta$ represents fractional surface coverage
	$K_{FG}$ represents Fowler-Guggenheim equilibrium constant
	$W$ represents interaction energy
	$R$ represents molar gas constant
	$T$ represents temperature
Fowler-Guggenheim equilibrium constant		output
fractional surface coverage	$\theta \equiv \frac{q_e}{q_m}$	input
	$\theta \equiv \frac{V}{V_m}$
	$\theta$ represents fractional surface coverage
	$q_e$ represents adsorbed solute (equilibrium)
	$q_m$ represents maximum monolayer adsorption capacity
	$V$ represents adsorbed gas volume (equlibrium)
	$V_m$ represents maximum monolayer adsorption volume
solute concentration (equilibrium)		input
interaction energy		output

Further links

Item	Property
Fowler-Guggenheim isotherm model	used by
nonlinear parameter estimation (Fowler-Guggenheim isotherm model)	linearized by

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