Linear parameter estimation (Temkin isotherm model)

linear estimation of Temkin isotherm parameters

computational task, linear task

MaRDI QIDQ6820957FDOCommunityMathModDB

Named after

Mikhail Temkin

Description

This task performs linear parameter estimation using adsorption equilibrium data by applying the linearized form of the Temkin isotherm. By plotting fractional coverage against the natural logarithm of solute concentration, the slope and intercept allow direct estimation of the adsorption-energy variation and the Temkin equilibrium constant. Although convenient, the linear method may introduce statistical bias due to transformation of variables. Nevertheless, it is widely used for rapid assessment of Temkin parameters in adsorption analysis. This approach is especially common in environmental and chemical engineering studies of pollutant adsorption.

Contained entities

adsorption energy variation		output
fractional surface coverage	$\theta \equiv \frac{q_e}{q_m}$	input
	$\theta \equiv \frac{V}{V_m}$
	$\theta$ represents fractional surface coverage
	$q_e$ represents adsorbed solute (equilibrium)
	$q_m$ represents maximum monolayer adsorption capacity
	$V$ represents adsorbed gas volume (equlibrium)
	$V_m$ represents maximum monolayer adsorption volume
solute concentration (equilibrium)		input
Temkin equilibrium constant		output
linear Temkin isotherm equation	$\theta =\frac{RT}{\mathrm{\Delta }Q}\ln (K_0)+\frac{RT}{\mathrm{\Delta }Q}\ln (C_e)$
	$\theta$ represents fractional surface coverage
	$C_e$ represents solute concentration (equilibrium)
	$K_0$ represents Temkin equilibrium constant
	$\mathrm{\Delta }Q$ represents adsorption energy variation
	$T$ represents temperature
	$R$ represents molar gas constant

Further links

Item	Property
nonlinear parameter estimation (Temkin isotherm model)	linearized by
Temkin isotherm model	used by

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