linear rotor (apolar)

Community: MathModDB

mathematical model

Available identifiers

MaRDI QIDQ6675422

mathematical model of an apolar linear molecule as a rigid rotor, interacting through its induced dipole moment with electric fields

List of contained entities

molecular alignment	$A=⟨\psi |{\cos }^2\theta |\psi ⟩$
	$\psi$ represents quantum state
	$\theta$ represents polar angle
molecular orientation	$O=⟨\psi |\cos \theta |\psi ⟩$
	$\psi$ represents quantum state
	$\theta$ represents polar angle
quantum Hamiltonian (electric polarizability)	$H=H_0-\frac{1}{2}\alpha {ℰ}^2$
	$H$ represents Hamiltonian operator
	$H_0$ represents Hamiltonian operator
	$\alpha$ represents polarizability
	$ℰ$ represents electric field
quantum Hamiltonian (linear rotor)	$\hat{H}=B{\hat{J}}^2$
	$B$ represents rotational constant
	$J$ represents angular momentum operator
	$\hat{H}$ represents Hamiltonian operator

List of computational tasks

optimal control

quantum stationary states

quantum time evolution

Further items linking to linear rotor (apolar)

Item	Property
linear rotor	specialized by
linear rotor (combined)	specialized by
molecular rotation	modelled by

This page was built for model: linear rotor (apolar)