linear rotor (combined)

Community: MathModDB

mathematical model

Available identifiers

MaRDI QIDQ6675424

mathematical model of a polar linear molecule as a rigid rotor, interacting through both its permanent and induced electric dipole moment with electric fields

Description

Note that under certain circumstances analytical solutions to the TISE are available for a finite number of low energy states (conditional quasi-exact solutions).

List of contained entities

molecular alignment	$A=⟨\psi |{\cos }^2\theta |\psi ⟩$
	$\psi$ represents quantum state
	$\theta$ represents polar angle
molecular orientation	$O=⟨\psi |\cos \theta |\psi ⟩$
	$\psi$ represents quantum state
	$\theta$ represents polar angle
quantum Hamiltonian (electric dipole)	$H=H_0-\mu \cdot ℰ$
	$H$ represents quantum Hamiltonian (electric dipole)
	$H_0$ represents Hamiltonian operator
	$ℰ$ represents electric field
	$\mu$ represents electric dipole moment
quantum Hamiltonian (electric polarizability)	$H=H_0-\frac{1}{2}\alpha {ℰ}^2$
	$H$ represents Hamiltonian operator
	$H_0$ represents Hamiltonian operator
	$\alpha$ represents polarizability
	$ℰ$ represents electric field
quantum Hamiltonian (linear rotor)	$\hat{H}=B{\hat{J}}^2$
	$B$ represents rotational constant
	$J$ represents angular momentum operator
	$\hat{H}$ represents Hamiltonian operator

List of computational tasks

optimal control

quantum conditional quasi-solvability

quantum stationary states

quantum time evolution

Mathematical models specializing linear rotor (combined)

linear rotor (apolar)

linear rotor (polar)

Further items linking to linear rotor (combined)

Item	Property
molecular rotation	modelled by

This page was built for model: linear rotor (combined)