normal mode (harmonic)

mathematical model

Available identifiers

describing molecular vibrations of many-body systems in terms of normal modes, within the harmonic approximation

quantum Hamiltonian (normal mode, harmonic)	$\hat{H} = \frac{1}{2} \sum_{i = 1}^{3 N - 6} ω_{i} ({\hat{p}}_{i}^{2} + {\hat{q}}_{i}^{2})$
	$N$ represents number of particles
	$\hat{H}$ represents Hamiltonian operator
	$ω$ represents vibration frequency (harmonic)
	$\hat{p}$ represents normal mode momentum (dimensionless)
	$\hat{q}$ represents normal coordinate (dimensionless)

quantum eigen energy (harmonic)	$E_{n} = \sum_{r = 1}^{3 N - 6} (n_{r} + \frac{1}{2}) ℏ ω_{r}$
	$E$ represents quantum eigen energy
	$N$ represents number of particles
	$ℏ$ represents reduced Planck constant
	$ω$ represents vibration frequency (harmonic)
	$n$ represents quantum number

This page was built for model: normal mode (harmonic)