Flory-Huggins isotherm model

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Model:6820981


Community: MathModDB

deterministic model dimensional model mathematical model nonlinear model static model

Available identifiers

MaRDI QIDQ6820981

adsorption model for multi-site occupancy and chain effects, named after Maurice Loyal Huggins, Paul Flory




The Flory–Huggins isotherm is an empirical adsorption model adapted from polymer solution theory that describes how chemically similar molecules of different chain length occupy adsorbent sites. It uses a coverage degree defined from initial and equilibrium concentrations and explicitly accounts for an occupancy number that represents how many adsorbate units occupy a site. The model is used to assess adsorption feasibility and spontaneity via an equilibrium constant that can be related to a standard Gibbs free-energy expression. It is applied when adsorbate molecules are large or chain-like (e.g., polymers, large organics) and the adsorbate–adsorbent arrangement is approximately random.

List of contained entities

Flory-Huggins equation θC0=KFH(1θ)nm
C0 represents initial solute concentration
θ represents degree of surface coverage
KFH represents Flory-Huggins equilibrium parameter
nm represents Flory-Huggins occupancy number

List of computational tasks

linear parameter estimation (Flory-Huggins model)
nonlinear parameter estimation (Flory-Huggins model)

Described at:

Monolayer and multilayer adsorption isotherm models for sorption from aqueous media (review)





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