Non-equilibrium relation between mobility and diffusivity of interacting Brownian particles under shear

DOI10.1143/PTPS.184.172MaRDI QIDQ3162900zbMATH OpenOpenAlexFDO

Authors Matthias Krüger, Matthias Fuchs

Publication date 22 October 2010

Published in Progress of Theoretical Physics Supplement (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/0911.1632

zbMATH Keywords

Brownian particleEinstein relationfluctuation dissipation theorem

Mathematics Subject Classification ID

Brownian motion (60J65) Dynamic and nonequilibrium phase transitions (general) in statistical mechanics (82C26) Statistical mechanics of solids (82D20)

Abstract: We investigate the relation between mobility and diffusivity for Brownian particles under steady shear near the glass transition, using mode coupling approximations. For the two directions perpendicular to the shear direction, the particle motion is diffusive at long times and the mobility reaches a finite constant. Nevertheless, the Einstein relation holds only for the short-time in-cage motion and is violated for long times. In order to get the relation between diffusivity and mobility, we perform the limit of small wavevector for the relations derived previously [Phys. Rev. Lett. 102 (2009), 135701], without further approximation. We find good agreement to simulation results. Furthermore, we split the extra term in the mobility in an exact way into three terms. Two of them are expressed in terms of mean squared displacements. The third is given in terms of the (less handy) force-force correlation function.

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• The modified Sutherland-Einstein relation for diffusive non-equilibria
• The effect of Brownian diffusion on shear-induced coagulation of colloidal dispersions
• Applications of Wiener’s Path Integral for the Diffusion of Brownian Particles in Shear Flows
• Generalized Einstein relation in an aging colloidal glass
• Nonequilibrium linear response for Markov dynamics. II: Inertial dynamics

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