Nonequilibrium thermodynamics of colloids

DOI10.1016/S0378-4371(01)00554-4MaRDI QIDQ5959002zbMATH OpenOpenAlexFDO

Authors D. Bedeaux, J. M. Rubi

Publication date 20 March 2002

Published in Physica A (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/cond-mat/0003308

zbMATH Keywords

effective viscosity coefficientinternal variablesOnsager coefficients

Mathematics Subject Classification ID

Irreversible thermodynamics, including Onsager-Machlup theory (82C35) Statistical mechanics of random media, disordered materials (including liquid crystals and spin glasses) (82D30)

Abstract: The common rules of classical nonequilibrium thermodynamics do not allow an Onsager coefficient like the viscosity to depend on the shear rate. Such a dependence is experimentally well documented, however. In this paper it is shown, using nonequilibrium thermodynamics alone, how it is possible that the effective viscosity coefficient of an isotropic colloidal system depends on both the shear rate and the frequency.

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Cites work

• Rheology of a dilute suspension of axisymmetric Brownian particles

Cited in

(11)

• Steady state viscosity coefficients of charged colloidal systems
• Critical conditions of entropy-driving nucleation in binary colloidal system
• Statistical physics approach to thermophoresis of colloids
• Thermophoresis and the effect of hydrodynamic interactions in a linear model for colloids
• Statistical mechanics of colloids and Boltzmann’s definition of the entropy
• Heat dissipation rate in a nonequilibrium viscoelastic medium
• Non-equilibrium pair interactions in colloidal dispersions
• Probability density functions of work and heat near the stochastic resonance of a colloidal particle
• A two-phase thermomechanical theory for granular suspensions
• Viscoelastic materials with anisotropic rigid particles: stress-deformation behavior
• Shear induced diffusion in viscoelastic materials with anisotropic rigid particles

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