nonlinear parameter estimation (Redlich-Peterson model)

Community: MathModDB

computational task

nonlinear task

Available identifiers

MaRDI QIDQ6821119 FDOQ6821119

nonlinear estimation of Redlich-Peterson model parameters, named after David L. Peterson, Otto Redlich

Description

This task performs nonlinear parameter estimation using experimental adsorption equilibrium data. The objective is to determine the Redlich-Peterson constant, coefficient, and exponent by directly fitting the nonlinear Redlich-Peterson equation to measured solute concentration and adsorbed amount data. Nonlinear regression preserves the full hybrid functional form, allowing the model to transition smoothly between Langmuir-like and Freundlich-like behavior. The resulting parameters quantify adsorption affinity, heterogeneity, and the degree of deviation from ideal monolayer adsorption.

List of contained entities

Redlich-Peterson coefficient
Redlich-Peterson constant
Redlich-Peterson equation	$q_e=\frac{A{C}_e}{1+B{C}_e^{\beta }}$
	$q_e$ represents adsorbed solute (equilibrium)
	$C_e$ represents solute concentration (equilibrium)
	$A$ represents Redlich-Peterson constant
	$B$ represents Redlich-Peterson coefficient
	$\beta$ represents Redlich-Peterson exponent
Redlich-Peterson exponent
Redlich-Peterson exponent constraint	$0\le \beta \le 1$	constraint
	$\beta$ represents Redlich-Peterson exponent
adsorbed solute (equilibrium)
solute concentration (equilibrium)

Computational tasks specializing nonlinear parameter estimation (Redlich-Peterson model)

linear parameter estimation (Freundlich isotherm)

linear parameter estimation (Henry's isotherm)

nonlinear parameter estimation (Langmuir adsorption model)

Further items linking to nonlinear parameter estimation (Redlich-Peterson model)

Item	Property
Redlich-Peterson isotherm model	used by

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