Nonlinear parameter estimation (Flory-Huggins model)

nonlinear estimation of Flory–Huggins parameters

computational task, nonlinear task

MaRDI QIDQ6820982FDOCommunityMathModDB

Named after

Paul Flory, Maurice Loyal Huggins

Description

This task fits the nonlinear Flory–Huggins equation to adsorption data to estimate the Flory–Huggins equilibrium constant and the occupancy number. It uses experimental initial and equilibrium concentrations and measured uptake to directly obtain parameter estimates without data linearization. The outputs quantify the effective site occupancy per adsorbate and the equilibrium parameter used to evaluate spontaneity.

Contained entities

Flory-Huggins equilibrium parameter		output
initial solute concentration		input
degree of surface coverage	$\theta \equiv 1-\frac{C_e}{C_0}$	input
	$C_0$ represents initial solute concentration
	$C_e$ represents solute concentration (equilibrium)
	$\theta$ represents degree of surface coverage
Flory-Huggins occupancy number		output
Flory-Huggins equation	$\frac{\theta }{C_0}=K_{FH}(1-\theta {)}^{n_m}$
	$C_0$ represents initial solute concentration
	$\theta$ represents degree of surface coverage
	$K_{FH}$ represents Flory-Huggins equilibrium parameter
	$n_m$ represents Flory-Huggins occupancy number

Further links

Item	Property
Flory-Huggins isotherm model	used by

---

---

Edit nonlinear parameter estimation (Flory-Huggins model) item

This page was built for task: nonlinear parameter estimation (Flory-Huggins model)