Nonlinear parameter estimation (Jossens model)

nonlinear estimation of Jossens isotherm parameters

Description

This task performs nonlinear parameter estimation using adsorption equilibrium data from solution-phase systems. The objective is to determine the Jossens equilibrium constant, interaction coefficient, and heterogeneity exponent by fitting the nonlinear Jossens adsorption equation to measured solute concentration and adsorbed amount data. The fitting preserves the exponential structure of the model and captures energetic heterogeneity of adsorption sites. At low adsorption levels, the task ensures consistency with Henry-type behavior. The estimated parameters characterize both adsorption affinity and the distribution of surface interaction energies.

Contained entities

Jossens equilibrium constant		output
adsorbed solute (equilibrium)		input
Jossens heterogeneity exponent constraint	$0 < p < 1$	constraint
	$p$ represents Jossens heterogeneity exponent

solute concentration (equilibrium)		input
Jossens heterogeneity exponent		output
Jossens energy parameter		output
Jossens isotherm equation	$C_{e} = \frac{q_{e}}{H} e^{F q_{e}^{p}}$
	$C_{e}$ represents solute concentration (equilibrium)
	$q_{e}$ represents adsorbed solute (equilibrium)
	$p$ represents Jossens heterogeneity exponent
	$F$ represents Jossens energy parameter
	$H$ represents Jossens equilibrium constant
	$H$ represents Jossens equilibrium constant

Specializations

linear parameter estimation (Henry's isotherm)

Further links

Item	Property
Jossens isotherm model	used by

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