nonlinear parameter estimation (Jossens model)

Community: MathModDB

computational task

nonlinear task

Available identifiers

MaRDI QIDQ6821207 FDOQ6821207

nonlinear estimation of Jossens isotherm parameters

Description

This task performs nonlinear parameter estimation using adsorption equilibrium data from solution-phase systems. The objective is to determine the Jossens equilibrium constant, interaction coefficient, and heterogeneity exponent by fitting the nonlinear Jossens adsorption equation to measured solute concentration and adsorbed amount data. The fitting preserves the exponential structure of the model and captures energetic heterogeneity of adsorption sites. At low adsorption levels, the task ensures consistency with Henry-type behavior. The estimated parameters characterize both adsorption affinity and the distribution of surface interaction energies.

List of contained entities

Jossens energy parameter
Jossens equilibrium constant
Jossens heterogeneity exponent
Jossens heterogeneity exponent constraint	$0<p<1$	constraint
	$p$ represents Jossens heterogeneity exponent
Jossens isotherm equation	$C_e=\frac{q_e}{H}{e}^{F{q}_e^p}$
	$C_e$ represents solute concentration (equilibrium)
	$q_e$ represents adsorbed solute (equilibrium)
	$p$ represents Jossens heterogeneity exponent
	$F$ represents Jossens energy parameter
	$H$ represents Jossens equilibrium constant
	$H$ represents Jossens equilibrium constant
adsorbed solute (equilibrium)
solute concentration (equilibrium)

Computational tasks specializing nonlinear parameter estimation (Jossens model)

linear parameter estimation (Henry's isotherm)

Further items linking to nonlinear parameter estimation (Jossens model)

Item	Property
Jossens isotherm model	used by

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