Nonlinear parameter estimation (Jovanovic multilayer model) (nonlinear estimation of multilayer Jovanovic model parameters)

Community: MathModDB

computational task	nonlinear task

Available identifiers

MaRDI QIDQ6821060 FDOQ6821060

Description

This task performs nonlinear parameter estimation using equilibrium adsorption data. The objective is to determine the Jovanovic monolayer capacity together with the first-layer and multilayer adsorption constants by directly fitting the nonlinear multilayer Jovanovic equation to measurements of solute concentration and adsorbed amount. Unlike linearized approaches, nonlinear fitting preserves the intrinsic exponential structure of the multilayer model.

Contained entities

solute concentration (equilibrium)
maximum monolayer adsorption capacity
Jovanovic constant
adsorbed solute (equilibrium)
Jovanovic multilayer constant
multilayer Jovanovic equation	$q_{e} = q_{m} (1 - \exp (- K_{J} C_{e})) \exp (K_{J, m} C_{e})$
	$q_{e}$ represents adsorbed solute (equilibrium)
	$q_{m}$ represents maximum monolayer adsorption capacity
	$C_{e}$ represents solute concentration (equilibrium)
	$K_{J}$ represents Jovanovic constant
	$K_{J, m}$ represents Jovanovic multilayer constant

Computational tasks specializations

nonlinear parameter estimation (Jovanovic model)

Computational Task	Algorithmic Task

Further links

Item	Property
Jovanovic multilayer isotherm model	used by

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