One-dimensional fluids with second nearest-neighbor interactions

DOI10.1007/S10955-017-1908-6MaRDI QIDQ1703080zbMATH OpenOpenAlexFDO

Authors Riccardo Fantoni, Andres Santos

Publication date 1 March 2018

Published in Journal of Statistical Physics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1708.07477

zbMATH Keywords

Fisher-Widom linenearest-neighborsone-dimensional fluidsradial distribution functionsquare-well modeltwo-step model

Mathematics Subject Classification ID

Lattice systems (Ising, dimer, Potts, etc.) and systems on graphs arising in equilibrium statistical mechanics (82B20) Statistical mechanics of liquids (82D15)

Abstract: As is well known, one-dimensional systems with interactions restricted to first nearest neighbors admit a full analytically exact statistical-mechanical solution. This is essentially due to the fact that the knowledge of the first nearest-neighbor probability distribution function, $p_1(r)$, is enough to determine the structural and thermodynamic properties of the system. On the other hand, if the interaction between second nearest-neighbor particles is turned on, the analytically exact solution is lost. Not only the knowledge of $p_1(r)$ is not sufficient anymore, but even its determination becomes a complex many-body problem. In this work we systematically explore different approximate solutions for one-dimensional second nearest-neighbor fluid models. We apply those approximations to the square-well and the attractive two-step pair potentials and compare them with Monte Carlo simulations, finding an excellent agreement.

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Cited in

(6)

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• Triangle-well and ramp interactions in one-dimensional fluids: a fully analytic exact solution
• scientific article; zbMATH DE number 3913892 (Why is no real title available?)
• One-dimensional Janus fluids. Exact solution and mapping from the quenched to the annealed system
• Finite-size effects and thermodynamic limit in one-dimensional Janus fluids
• 1D fluids with repulsive nearest-neighbour interactions: low-temperature anomalies

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