PROPERTIES OF NONFREENESS: AN ENTROPY MEASURE OF ELECTRON CORRELATION

DOI10.1142/S0219749907003201MaRDI QIDQ3503058zbMATH OpenFDO

Authors Alex D. Gottlieb, N. J. Mauser

Publication date 20 May 2008

Published in International Journal of Quantum Information (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/quant-ph/0608171

zbMATH Keywords

correlation entropydensity operatorfermion correlationfermion Fock spacequasifree entropy

Mathematics Subject Classification ID

Quantum computation (81P68) Measures of information, entropy (94A17)

Abstract: "Nonfreeness" is the (negative of the) difference between the von Neumann entropies of a given many-fermion state and the free state that has the same 1-particle statistics. It also equals the relative entropy of the two states in question, i.e., it is the entropy of the given state relative to the corresponding free state. The nonfreeness of a pure state is the same as its "particle-hole symmetric correlation entropy", a variant of an established measure of electron correlation. But nonfreeness is also defined for mixed states, and this allows one to compare the nonfreeness of subsystems to the nonfreeness of the whole. Nonfreeness of a part does not exceed that in the whole; nonfreeness is additive over independent subsystems; and nonfreeness is superadditive over subsystems that are independent on the 1-particle level.

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Cites work

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• New Approach to the Theory of Superexchange Interactions
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Cited in

(5)

• \(q\)-Rényi's entropy as a possible measure of electron correlation
• The time-dependent Hartree-Fock-Bogoliubov equations for bosons
• One particle equations for many particle quantum systems: the MCTHDF method
• On the correlation entropy of discrete nanoelectronic systems
• An exact one-particle theory of bosonic excitations: from a generalized Hohenberg–Kohn theorem to convexified N-representability

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