Perturbation method with triangular propagators and anharmonicities of intermediate strength

DOI10.1023/A:1018852612649MaRDI QIDQ5934326zbMATH OpenOpenAlexFDO

Authors Miloslav Znojil

Publication date 19 June 2001

Published in Journal of Mathematical Chemistry (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/quant-ph/9910114

zbMATH Keywords

anharmonicityRayleigh-Schrödinger perturbation methodtriangular propagators

Mathematics Subject Classification ID

Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Perturbation theories for operators and differential equations in quantum theory (81Q15)

Abstract: I propose a new version of the Rayleigh - Schr"{o}dinger perturbation method. It admits a lower triangular matrix in place of the usual diagonal propagator. Illustrated on rational anharmonicities polynomial}(x)/polynomial}(x), treated as perturbations of (quasi-)exact anharmonic oscilators. In this sense the method works in an intermediate-coupling regime and bridges the gap between the weak- and strong-coupling expansions.

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Cited in

(11)

• Double well model \(V(r)=ar^2+br^4+cr^6\) with \(a<0\) and perturbation method with triangular propagators
• Properties of a class of perturbed Toeplitz periodic tridiagonal matrices
• On the determinant evaluation of quasi penta-diagonal matrices and quasi penta-diagonal Toeplitz matrices
• A fast method for solving quasi-pentadiagonal Toeplitz linear systems and its application to the Lax-Wendroff scheme
• Algebraic convergent perturbation theory for quantum systems with strong anharmonicity
• Theory and algorithm of the inversion method for pentadiagonal matrices
• A symbolic algorithm for periodic tridiagonal systems of equations
• A fast solver for pentadiagonal Toeplitz systems with multiple right-hand sides
• Generalized Sherman-Morrison-Woodbury formula based algorithm for the inverses of opposite-bordered tridiagonal matrices
• A fast algorithm for solving diagonally dominant symmetric quasi-pentadiagonal Toeplitz linear systems
• Perturbation method for non-square Hamiltonians and its application to polynomial oscillators

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