Pseudo-second-order adsorption parameter estimation

determination of rate constant and equilibrium capacity from time-resolved uptake data

computational task, discrete-time task, nonlinear task

Description

Estimation of the rate constant and the equilibrium adsorption capacity of the pseudo-second-order adsorption kinetic model from time-resolved uptake measurements. The model’s analytical solution is fitted to the measured amounts adsorbed at different contact times, typically by nonlinear least-squares regression. The initial amount adsorbed is usually fixed in advance, most often at zero for an initially unloaded adsorbent. The fitted parameters describe how fast the system approaches equilibrium and how much adsorbate the adsorbent can take up at equilibrium.

Contained Entity(-ies)

pseudo-second-order adsorption solution	$q (t) = \frac{q_{0} + k_{2} q_{e} (q_{e} - q_{0}) t}{1 + k_{2} (q_{e} - q_{0}) t}$	analytical solution
	$q$ represents adsorbed solute (time-dependent)
	$q_{e}$ represents adsorbed solute (equilibrium)
	$q_{0}$ represents adsorbed solute (initial)
	$k_{2}$ represents pseudo-second-order reaction rate constant
	$t$ represents time

adsorbed solute (equilibrium)		parameter
		numeric value 10.0
adsorbed solute (initial)		parameter
		numeric value 3.0
		numeric value 6.0
		numeric value 9.0
		numeric value 0.0
pseudo-second-order reaction rate constant		constant
		numeric value 0.2
time		input
		minimum value 0.0
		maximum value 5.0
		number of values 501
adsorbed solute (time-dependent)		output
adsorption condition for the initial uptake	$0 \leq q_{0} < q_{e}$	constraint
	$q_{0}$ represents adsorbed solute (initial)
	$q_{e}$ represents adsorbed solute (equilibrium)

Further link(s)

Item	Property
pseudo-second-order adsorption kinetic model	used by

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