Onsager reciprocity in premelting solids

DOI10.1007/S10955-009-9699-ZMaRDI QIDQ1024231zbMATH OpenOpenAlexFDO

Authors M. J. Spannuth, J. S. Wettlaufer, Stephen S. L. Peppin

Publication date 16 June 2009

Published in Journal of Statistical Physics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/0809.1287

zbMATH Keywords

diffusioncolloidsreciprocitySoret effectDufour effectpremeltingsurface phase transitions

Mathematics Subject Classification ID

Random walks, random surfaces, lattice animals, etc. in equilibrium statistical mechanics (82B41) Statistical mechanics of solids (82D20) Irreversible thermodynamics, including Onsager-Machlup theory (82B35)

Abstract: The diffusive motion of colloidal particles dispersed in a premelting solid is analyzed within the framework of irreversible thermodynamics. We determine the mass diffusion coefficient, thermal diffusion coefficient and Soret coefficient of the particles in the dilute limit, and find good agreement with experimental data. In contrast to liquid suspensions, the unique nature of premelting solids allows us to derive an expression for the Dufour coefficient and independently verify the Onsager reciprocal relation coupling diffusion to the flow of heat.

Recommendations

• Onsager reciprocity as a consequence of Maxwell reciprocity for ``equidiffuse fluids
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Cites work

• scientific article; zbMATH DE number 3119871 (Why is no real title available?)
• scientific article; zbMATH DE number 3181028 (Why is no real title available?)
• Colloidal Dispersions
• PREMELTING DYNAMICS
• Premelting dynamics in a continuum model of frost heave
• Reciprocal Relations in Irreversible Processes. II.

Cited in

(1)

• Insight into interrelation between single-particle and collective diffusion in binary melts

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