Thermodynamical entropy (and its additivity) within generalized thermodynamics

DOI10.1016/S0378-4371(03)00262-0MaRDI QIDQ1394673zbMATH OpenFDO

Authors D. Massart

Publication date 23 June 2003

Published in Physica A (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/cond-mat/0208064

zbMATH Keywords

finite heat bathsweakly interacting ergodic systems

Mathematics Subject Classification ID

Statistical thermodynamics (82B30)

Abstract: This is an analysis of the additivity of the entropy of thermodynamical systems with finite heat baths. It is presented an expression for the physical entropy of weakly interacting ergodic systems, and it is shown that it is valid for both the microcanonical (constant energy), the Boltzmann-Gibbs canonical (infinite heat bath) and the Tsallis (finite heat bath) ensembles. This physical entropy may be written as a variant of Tsallis entropy. It becomes an additive function after a suitable choice of additive constants, in a procedure reminiscent to the solution presented by Gibbs to the paradox bearing his name.

Recommendations

• Extensive statistical mechanics based on nonadditive entropy: canonical ensemble
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Cites work

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• scientific article; zbMATH DE number 3999395 (Why is no real title available?)
• scientific article; zbMATH DE number 3057307 (Why is no real title available?)
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• Possible generalization of Boltzmann-Gibbs statistics.
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Cited in

(9)

• Generalization of Gibbs entropy and thermodynamic relation
• Nonextensivity in nonequilibrium plasma systems with Coulombian long-range interactions
• Partial subadditivity of entropies
• Thermodynamic stability conditions for nonadditive composable entropies
• The nonadditive entropy S_q and its applications in physics and elsewhere: some remarks
• On the generalized entropy pseudoadditivity for complex systems
• Models of finite bath and generalised thermodynamics
• On the possible distributions of temperature in nonequilibrium steady states
• Microscopic interpretation of generalized entropy

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