Completely monotone solutions of the mode-coupling theory for mixtures

DOI10.1023/A:1019991729106zbMATH Open1027.82522arXivcond-mat/0202238MaRDI QIDQ1397448FDOQ1397448

Authors: Thomas Franosch, Th. Voigtmann 

Publication date: 6 August 2003

Published in: Journal of Statistical Physics (Search for Journal in Brave)

Abstract: We establish that a mode-coupling approximation for the dynamics of multi-component systems obeying Smoluchowski dynamics preserves a subtle yet fundamental property: the matrices of partial density correlation functions are completely monotone, i.e. they can exactly be written as superpositions of decaying exponentials only. This statement holds, no matter what further approximations are needed to calculate the theory's coupling parameters. The long-time limit of these functions fulfills a maximum property, and an iteration scheme for its numerical determination is given. We also show the existence of a unique solution to the equations of motion for which power series both for short times and small frequencies exist, the latter except at special points where ergodic-to-nonergodic transitions occur. These transitions are bifurcations that are proven to be of the cuspoid family.

Full work available at URL: https://arxiv.org/abs/cond-mat/0202238

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zbMATH Keywords

mode-coupling theoryGlass transitionSmoluchowski dynamicscompletely monotone functionsPerron-Frobenius mappings

Mathematics Subject Classification ID

Time-dependent statistical mechanics (dynamic and nonequilibrium) (82C99)

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• A certain class of completely monotonic sequences
• An Improved Integration Scheme for Mode-Coupling-Theory Equations
• Memory effects in colloidal motion under confinement and driving
• Mode-coupling theory for multiple decay channels
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• Glassy dynamics from generalized mode-coupling theory: existence and uniqueness of solutions for hierarchically coupled integro-differential equations
• Scaling equations for mode-coupling theories with multiple decay channels
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