Dimension-dependent two-electron Hamiltonian matrix elements

DOI10.1023/A:1019196719751MaRDI QIDQ1580236zbMATH OpenFDO

Authors J. H. Summerfield, J. G. Loeser

Publication date 19 July 2001

Published in Journal of Mathematical Chemistry (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1023/A:1019196719751

zbMATH Keywords

\(D\)-dependent hydrogenic wavefunctionsclosed form solutionselectron-electron interactions

Mathematics Subject Classification ID

Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Atomic physics (81V45)

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(3)

• A closed-form relation for dimension-dependent two-electron matrix elements of the interelectronic distance
• Analytic matrix elements for the two-electron atomic basis with logarithmic terms
• Gauging away the electron-electron interaction by the local phase of complex wave functions in two-electron systems

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