Node balanced steady states: unifying and generalizing complex and detailed balanced steady states
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Abstract: We introduce a unifying and generalizing framework for complex and detailed balanced steady states in chemical reaction network theory. To this end, we generalize the graph commonly used to represent a reaction network. Specifically, we introduce a graph, called a reaction graph, that has one edge for each reaction but potentially multiple nodes for each complex. A special class of steady states, called node balanced steady states, is naturally associated with such a reaction graph. We show that complex and detailed balanced steady states are special cases of node balanced steady states by choosing appropriate reaction graphs. Further, we show that node balanced steady states have properties analogous to complex balanced steady states, such as uniqueness and asymptotical stability in each stoichiometric compatibility class. Moreover, we associate an integer, called the deficiency, to a reaction graph that gives the number of independent relations in the reaction rate constants that need to be satisfied for a positive node balanced steady state to exist. The set of reaction graphs (modulo isomorphism) is equipped with a partial order that has the complex balanced reaction graph as minimal element. We relate this order to the deficiency and to the set of reaction rate constants for which a positive node balanced steady state exists.
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Cites work
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Cited in
(6)- The steady-state degree and mixed volume of a chemical reaction network
- The Disguised Toric Locus and Affine Equivalence of Reaction Networks
- Critical parameters for singular perturbation reductions of chemical reaction networks
- Graphically balanced equilibria and stationary measures of reaction networks
- A generalization of Birch's theorem and vertex-balanced steady states for generalized mass-action systems
- Detailed balance \(=\) complex balance \(+\) cycle balance: a graph-theoretic proof for reaction networks and Markov chains
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