Shannon entropies and Fisher information of K-shell electrons of neutral atoms

DOI10.1016/J.PHYSLETA.2017.12.005MaRDI QIDQ1700541zbMATH OpenOpenAlexFDO

Authors Golam Ali Sekh, Aparna Saha, B. Talukdar

Publication date 6 March 2018

Published in Physics Letters. A (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1710.05510

zbMATH Keywords

Shannon entropyFisher informationcorrelation effectcorrelated wave functionK-shell electrons

Mathematics Subject Classification ID

Measures of information, entropy (94A17) Atomic physics (81V45) Molecular physics (81V55)

Abstract: We represent the two K-shell electrons of neutral atoms by Hylleraas-type wave function which fulfils the exact behavior at the electron-electron and electron-nucleus coalescence points and, derive a simple method to construct expressions for single-particle position- and momentum-space charge densities, $ho(vecr)$ and $gamma(vecp)$ respectively. We make use of the results for $ho(vecr)$ and $gamma(vecp)$ to critically examine the effect of correlation on bare (uncorrelated) values of Shannon information entropies ($S$) and of Fisher information ($F$) for the K-shell electrons of atoms from helium to neon. Due to inter-electronic repulsion the values of the uncorrelated Shannon position-space entropies are augmented while those of the momentum-space entropies are reduced. The corresponding Fisher information are found to exhibit opposite behavior in respect of this. Attempts are made to provide some plausible explanation for the observed response of $S$ and $F$ to electronic correlation.

Recommendations

• The Fisher-Shannon information plane for atoms
• Statistical complexity and Fisher-Shannon information in the H-atom
• Fisher-Shannon plane and statistical complexity of atoms
• Electron density and Fisher information of Dirac-Fock atoms
• Net Fisher information measure versus ionization potential and dipole polarizability in atoms

Cites work

• scientific article; zbMATH DE number 3116475 (Why is no real title available?)
• scientific article; zbMATH DE number 3220189 (Why is no real title available?)
• scientific article; zbMATH DE number 3285978 (Why is no real title available?)
• A Mathematical Theory of Communication
• Correlated Orbitals for the Ground State of Heliumlike Systems
• Science from Fisher Information
• The Fisher-information-based uncertainty relation, Cramer–Rao inequality and kinetic energy for theD-dimensional central problem

Cited in

(18)

• Fisher information for endohedrally confined hydrogen atom
• Effects of global monopole on thermodynamic properties and Shannon entropy under a Mie-type potential
• Net Fisher information measure versus ionization potential and dipole polarizability in atoms
• Statistical complexity and Fisher-Shannon information in the H-atom
• Shannon entropy and Fisher information for endohedral confined one- and two-electron atoms
• Shannon information entropy for a one-dimensional ionic crystal
• Insights from intracules and Coulomb holes
• Electron density and Fisher information of Dirac-Fock atoms
• An approach to local electron energy in atoms through Rényi's entropy
• FISHER-SHANNON ENTROPIC UNCERTAINTY RELATIONS AND THEIR POWER-PRODUCTS AS A MEASURE OF ELECTRONIC CORRELATION
• Shannon and Fisher entropies for a hydrogen atom under soft spherical confinement
• Calculation of von Neumann entropy for hydrogen and positronium negative ions
• Local wave-vector, Shannon and Fisher information
• Characterization of the Chandrasekhar correlated two-electron wavefunction using Fisher, Shannon and statistical complexity information measures
• The Fisher-Shannon information plane for atoms
• Position-momentum correlations in the Moshinsky atom
• Fisher information for the Morse oscillator
• Rényi information of atoms

This page was built for publication: Shannon entropies and Fisher information of K-shell electrons of neutral atoms

Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q1700541)