Hypervirial theorems

zbMATH Open0615.46069MaRDI QIDQ1820403FDOQ1820403

Authors: Francisco M. Fernández, Eduardo A. Castro 

Publication date: 1987

Published in: Lecture Notes in Chemistry (Search for Journal in Brave)

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zbMATH Keywords

boundary conditionsstatistical quantum mechanicsquantum chemistrysemi-classical approximationdiagonal formcommutation relationhypervirial theoremapproximation of the actual wave functionhamiltonian operatorN-particle systemoptimize trial functions in variational approximationsRayleigh-Schrödinger perturbation theory

Mathematics Subject Classification ID

Perturbation theory of linear operators (47A55) Perturbation theories for operators and differential equations in quantum theory (81Q15) Commutation relations and statistics as related to quantum mechanics (general) (81S05) Research exposition (monographs, survey articles) pertaining to functional analysis (46-02) Quantum equilibrium statistical mechanics (general) (82B10) Miscellaneous applications of functional analysis (46N99)

Cited In (9)

• Algebraic derivation of Kramers–Pasternack relations based on the Schrödinger factorization method
• Virial theorem and hypervirial theorem in a spherical geometry
• Hellmann-Feynman connection for the relative Fisher information
• Fisher information framework for time series modeling
• The hypervirial and viral theorems in terms of Weyl symbols
• The HVT technique and the treatment of two basic inequalities
• Application of the quantum mechanical hyperviral theorems to even-power series potentials
• Energy of a perturbed rigid rotor
• Hypervirial perturbation theory revisited

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