Geometry of thermodynamic states

DOI10.1016/S0375-9601(98)00385-5MaRDI QIDQ1966762zbMATH OpenOpenAlexFDO

Authors Dorje C. Brody, Lane P. Hughston

Publication date 8 March 2000

Published in Physics Letters. A (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/quant-ph/9706030

zbMATH Keywords

uncertainty relationscanonical distributionthermodynamic statesgeometric formalism for statistical estimation

Mathematics Subject Classification ID

General and philosophical questions in quantum theory (81P05) Classical equilibrium statistical mechanics (general) (82B05)

Abstract: A novel geometric formalism for statistical estimation is applied here to the canonical distribution of classical statistical mechanics. In this scheme thermodynamic states, or equivalently, statistical mechanical states, can be characterised concisely in terms of the geometry of a submanifold $calM$ of the unit sphere $calS$ in a real Hilbert space $calH$. The measurement of a thermodynamic variable then corresponds to the reduction of a state vector in $calH$ to an eigenstate, where the transition probability is the Boltzmann weight. We derive a set of uncertainty relations for conjugate thermodynamic variables in the equilibrium thermodynamic states. These follow as a consequence of a striking thermodynamic analogue of the Anandan-Aharonov relations in quantum mechanics. As a result we are able to provide a resolution to the controversy surrounding the status of `temperature fluctuations' in the canonical ensemble. By consideration of the curvature of the thermodynamic trajectory in its state space we are then able to derive a series of higher order variance bounds, which we calculate explicitly to second order.

Recommendations

• Geometrization of statistical mechanics
• Statistical geometry in quantum mechanics
• On the geometrical structure of the generalized quantum Gibbs states
• Geometrical structure of the state space in classical statistical and phenomenological thermodynamics
• Geometry of canonical correlation on the state space of a quantum system

Cites work

• scientific article; zbMATH DE number 780717 (Why is no real title available?)
• scientific article; zbMATH DE number 815101 (Why is no real title available?)
• Generalised Heisenberg relations for quantum statistical estimation
• Geometry of Quantum Statistical Inference
• Geometry of quantum evolution
• Informative geometry of probability spaces
• Postulates for general quantum mechanics

Cited in

(12)

• Geometrization of statistical mechanics
• On the geometrical representation of classical statistical mechanics
• Thermodynamic geometry, transition between attractive and repulsive interactions and condensation of dual statistics
• Geometric measure theory and the axioms of continuum thermodynamics
• Geometry of basic statistical physics mapping
• Geometrical aspects and connections of the energy–temperature fluctuation relation
• Geometrothermodynamics of black holes
• On the geometric structure of thermodynamics
• Geometric quantum mechanics
• The Geometry of Some Thermodynamic Systems
• Geometrothermodynamic description of real gases using the law of corresponding states
• Thermodynamics as a theory of measurement

This page was built for publication: Geometry of thermodynamic states

Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q1966762)