Triangle-well and ramp interactions in one-dimensional fluids: a fully analytic exact solution

DOI10.1007/S10955-019-02255-XzbMATH Open1419.82067arXiv1812.01268OpenAlexW2903434764MaRDI QIDQ2000723FDOQ2000723

Ana M. Montero, Andres Santos

Publication date: 28 June 2019

Published in: Journal of Statistical Physics (Search for Journal in Brave)

Abstract: The exact statistical-mechanical solution for the equilibrium properties, both thermodynamic and structural, of one-dimensional fluids of particles interacting via the triangle-well and the ramp potentials is worked out. In contrast to previous studies, where the radial distribution function $g(r)$ was obtained numerically from the structure factor by Fourier inversion, we provide a fully analytic representation of $g(r)$ up to any desired distance. The solution is employed to perform an extensive study of the equation of state, the excess internal energy per particle, the residual multiparticle entropy, the structure factor, the radial distribution function, and the direct correlation function. In addition, scatter plots of the bridge function versus the indirect correlation function are used to gauge the reliability of the hypernetted-chain, Percus--Yevick, and Martynov--Sarkisov closures. Finally, the Fisher--Widom and Widom lines are obtained in the case of the triangle-well model.

Full work available at URL: https://arxiv.org/abs/1812.01268

zbMATH Keywords

nearest neighborsradial distribution functionWidom lineFisher-Widom lineone-dimensional fluidsramp modeltriangle-well model

Mathematics Subject Classification ID

Interacting particle systems in time-dependent statistical mechanics (82C22) Statistical mechanics of liquids (82D15)

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Cited In (2)

• Finite-size effects and thermodynamic limit in one-dimensional Janus fluids
• One-dimensional Janus fluids. Exact solution and mapping from the quenched to the annealed system

Uses Software

• Wolfram Demonstrations

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