A nonequilibrium extension of the Clausius heat theorem

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Publication:2016513

DOI10.1007/S10955-013-0822-9zbMATH Open1291.82105arXiv1206.3423OpenAlexW2095994948MaRDI QIDQ2016513FDOQ2016513


Authors: Karel Netočný, Christian Maes Edit this on Wikidata


Publication date: 20 June 2014

Published in: Journal of Statistical Physics (Search for Journal in Brave)

Abstract: We generalize the Clausius (in)equality to overdamped mesoscopic and macroscopic diffusions in the presence of nonconservative forces. In contrast to previous frameworks, we use a decomposition scheme for heat which is based on an exact variant of the Minimum Entropy Production Principle as obtained from dynamical fluctuation theory. This new extended heat theorem holds true for arbitrary driving and does not require assumptions of local or close to equilibrium. The argument remains exactly intact for diffusing fields where the fields correspond to macroscopic profiles of interacting particles under hydrodynamic fluctuations. We also show that the change of Shannon entropy is related to the antisymmetric part under a modified time-reversal of the time-integrated entropy flux.


Full work available at URL: https://arxiv.org/abs/1206.3423




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