A nonequilibrium extension of the Clausius heat theorem
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Publication:2016513
DOI10.1007/S10955-013-0822-9zbMATH Open1291.82105arXiv1206.3423OpenAlexW2095994948MaRDI QIDQ2016513FDOQ2016513
Authors: Karel Netočný, Christian Maes
Publication date: 20 June 2014
Published in: Journal of Statistical Physics (Search for Journal in Brave)
Abstract: We generalize the Clausius (in)equality to overdamped mesoscopic and macroscopic diffusions in the presence of nonconservative forces. In contrast to previous frameworks, we use a decomposition scheme for heat which is based on an exact variant of the Minimum Entropy Production Principle as obtained from dynamical fluctuation theory. This new extended heat theorem holds true for arbitrary driving and does not require assumptions of local or close to equilibrium. The argument remains exactly intact for diffusing fields where the fields correspond to macroscopic profiles of interacting particles under hydrodynamic fluctuations. We also show that the change of Shannon entropy is related to the antisymmetric part under a modified time-reversal of the time-integrated entropy flux.
Full work available at URL: https://arxiv.org/abs/1206.3423
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Cited In (21)
- Quantitative analysis of the Clausius inequality
- Excess entropy production in quantum system: quantum master equation approach
- Geometric thermodynamics for the Fokker-Planck equation: stochastic thermodynamic links between information geometry and optimal transport
- Close-to-equilibrium heat capacity
- Calorimetry for active systems
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- The Clausius inequality: implications for non-equilibrium thermodynamic steady states with NEMD corroboration
- Heat bounds and the blowtorch theorem
- Equivalent definitions of the quantum nonadiabatic entropy production
- Revisiting the Glansdorff-Prigogine criterion for stability within irreversible thermodynamics
- Entropy and nonlinear nonequilibrium thermodynamic relation for heat conducting steady states
- Extended Clausius relation and entropy for nonequilibrium steady states in heat conducting quantum systems
- On baricenters of heating measures and thermodynamical inequalities
- Analysis of slow transitions between nonequilibrium steady states
- Optimal thermodynamic uncertainty relation in Markov jump processes
- Nonequilibrium entropies
- Minimum entropy production, detailed balance and Wasserstein distance for continuous-time Markov processes
- A general fluctuation-response relation for noise variations and its application to driven hydrodynamic experiments
- Information geometry, trade-off relations, and generalized Glansdorff-Prigogine criterion for stability
- Global thermodynamics for heat conduction systems
- Exact equalities and thermodynamic relations for nonequilibrium steady states
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