Convergence of cluster and virial expansions for repulsive classical gases
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Publication:2175124
Partitions of sets (05A18) Graph labelling (graceful graphs, bandwidth, etc.) (05C78) Classical equilibrium statistical mechanics (general) (82B05) Continuum models (systems of particles, etc.) arising in equilibrium statistical mechanics (82B21) Phase transitions (general) in equilibrium statistical mechanics (82B26)
Abstract: We study the convergence of cluster and virial expansions for systems of particles subject to positive two-body interactions. Our results strengthen and generalize existing lower bounds on the radii of convergence and on the value of the pressure. Our treatment of the cluster coefficients is based on expressing the truncated weights in terms of trees and partition schemes, and generalize to soft repulsions previous approaches for models with hard exclusions. Our main theorem holds in a very general framework that does not require translation invariance and is applicable to models in general measure spaces. For the virial coefficients we resort to an approach due to Ramawadth and Tate that uses Lagrange inversion techniques only at the level of formal power series and leads to diagrammatic expressions in terms of trees, rather than the doubly connected diagrams traditionally used. We obtain a new criterion that strengthens, for repulsive interactions, the best criterion previously available (proposed by Groenveld and proven by Ramawadth and Tate). We illustrate our results with a few applications showing noticeable improvements in the lower bound of convergence radii.
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Cited in
(26)- Multispecies virial expansions
- Virial inversion and density functionals
- The virial series for a gas of particles with uniformly repulsive pairwise interaction and its relation with the approach to the mean field
- Virial expansions for correlation functions in canonical ensemble
- Reduced Density Matrices of Quantum Gases. I. Limit of Infinite Volume
- Classical particles in the continuum subjected to high density boundary conditions
- Numerical evaluation of second and third virial coefficients of some inert gases via classical cluster expansion
- The Mayer series of the Lennard-Jones gas: improved bounds for the convergence radius
- Virial series for a system of classical particles interacting through a pair potential with negative minimum
- Cluster and virial expansions for the multi-species Tonks gas
- Revisiting Groeneveld's approach to the virial expansion
- A path-integral analysis of interacting Bose gases and loop gases
- Transition to the condensate state for classical gases and clusterization
- New distribution formulas for classical gas, clusters, and phase transitions
- High-temperature cluster expansion for classical and quantum spin lattice systems with multi-body interactions
- On the zeroes of hypergraph independence polynomials
- Quasipolynomial-time algorithms for Gibbs point processes
- An inverse cluster expansion for the chemical potential
- Strong spatial mixing for repulsive point processes
- Correlation decay for hard spheres via Markov chains
- The virial expansion of a classical interacting system
- Potential-weighted connective constants and uniqueness of Gibbs measures
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- Analyticity for classical gasses via recursion
- Cluster expansions: necessary and sufficient convergence conditions
- On the convergence of cluster expansions for polymer gases
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