Kinetic theory of dense fluids. IV: Entropy balance equation and irreversible thermodynamics

DOI10.1016/0003-4916(79)90399-3MaRDI QIDQ2266634zbMATH OpenOpenAlexFDO

Authors Byung Chan Eu

Publication date 1979

Published in Annals of Physics (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1016/0003-4916(79)90399-3

zbMATH Keywords

entropy balance equationentropy fluxentropy productionglobal entropy formulakinetic equationlocal entropy densitymacroscopic constitutive functionalsreal fluids

Mathematics Subject Classification ID

Foundations of fluid mechanics (76A02) Rarefied gas flows, Boltzmann equation in fluid mechanics (76P05) Statistical mechanics of liquids (82D15)

Review text

[For part I, II and III see: ibid. 118, 187-229 (1979; Zbl 0436.76001); ibid. 118, 230-245 (1979; Zbl 0436.76002); ibid. 120, 423-455 (1979; Zbl 0451.76004).] By making use of the kinetic equation and the global entropy formula reported in the first paper of this series, we have derived the entropy balance equation and the accompanying molecular formulas for local entropy density, entropy flux and entropy production for real fluids at an arbitrary density. We have thereby obtained an extension to real fluids of the Boltzmannian irreversible thermodynamics which is based on the Boltzmann equation for ideal fluids. The theory presented provides us with a molecular basis for the continuum mechanics formulation of irreversible thermodynamics by Coleman, Noll, Gurtin and their coworkers [see e.g.: \textit{B. D. Coleman} and \textit{W. Noll}, Arch. Ration. Mech. Anal. 13, 167-178 (1963; Zbl 0113.178)]: The macroscopic constitutive functionals in their theory can now be calculated from the various molecular formulas for the relevant quantities in our theory.

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Cited in

(4)

• Entropy principle and recent results in non-equilibrium theories
• scientific article; zbMATH DE number 4131837 (Why is no real title available?)
• Entropy Functionals for Dense Fluids, Mixtures and Suspensions
• Irreversible thermodynamics of fluids

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