The role of normally hyperbolic invariant manifolds (NHIMS) in the context of the phase space setting for chemical reaction dynamics

DOI10.1134/S1560354716060034zbMath1369.34068MaRDI QIDQ2361632

Stephen Wiggins

Publication date: 30 June 2017

Published in: Regular and Chaotic Dynamics (Search for Journal in Brave)

zbMATH Keywords

normally hyperbolic invariant manifoldschemical reaction dynamicsdividing surfacephase space transportindex \(k\) saddle points

Mathematics Subject Classification ID

Topological structure of integral curves, singular points, limit cycles of ordinary differential equations (34C05) Classical flows, reactions, etc. in chemistry (92E20) Hamilton's equations (70H05) Perturbations of finite-dimensional Hamiltonian systems, normal forms, small divisors, KAM theory, Arnol'd diffusion (37J40) Chemical kinetics in thermodynamics and heat transfer (80A30) Qualitative investigation and simulation of ordinary differential equation models (34C60) Invariant manifolds for ordinary differential equations (34C45) Symmetries and conservation laws, reverse symmetries, invariant manifolds and their bifurcations, reduction for problems in Hamiltonian and Lagrangian mechanics (70H33)

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Cites Work

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• Transition states near rank-two saddles: correlated electron dynamics of helium
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• Direct construction of a dividing surface of minimal flux for multi-degree-of-freedom systems that cannot be recrossed
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• Bifurcations of transition states: Morse bifurcations
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