On chemisorption of polymers to solid surfaces

DOI10.1007/S10955-006-9224-6MaRDI QIDQ2641371zbMATH OpenOpenAlexFDO

Authors Radek Erban, S. Jonathan Chapman

Publication date 20 August 2007

Published in Journal of Statistical Physics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/physics/0609029

zbMATH Keywords

latticepolymerschemisorptionrandom sequential adsorptionirreversible

Mathematics Subject Classification ID

Dynamic lattice systems (kinetic Ising, etc.) and systems on graphs in time-dependent statistical mechanics (82C20) Statistical mechanics of polymers (82D60)

Abstract: The irreversible adsorption of polymers to a two-dimensional solid surface is studied. An operator formalism is introduced for chemisorption from a polydisperse solution of polymers which transforms the analysis of the adsorption process to a set of combinatorial problems on a two-dimensional lattice. The time evolution of the number of polymers attached and the surface area covered are calculated via a series expansion. The dependence of the final coverage on the parameters of the model (i.e. the parameters of the distribution of polymer lengths in the solution) is studied. Various methods for accelerating the convergence of the resulting infinite series are considered. To demonstrate the accuracy of the truncated series approach, the series expansion results are compared with the results of stochastic simulation.

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Cites work

• scientific article; zbMATH DE number 3114505 (Why is no real title available?)
• Equation-free, coarse-grained multiscale computation: enabling microscopic simulators to perform system-level analysis
• On a Device for Computing the e m (S n ) Transformation

Cited in

(4)

• A new approach to determination of the acid and base parameters of the surface free energy of polymers
• How polar hydroxyl groups affect surface hydrophobicity on model talc surfaces
• DYNAMICS OF POLYDISPERSE IRREVERSIBLE ADSORPTION: A PHARMACOLOGICAL EXAMPLE
• Random walk on semi-cylinders for diffusion problems with mixed Dirichlet-Robin boundary conditions

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