New formulation of statistical mechanics using thermal pure quantum states
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Publication:2928528
DOI10.1142/9789814602372_0018zbMATH Open1299.81037arXiv1312.5145OpenAlexW3104101211MaRDI QIDQ2928528FDOQ2928528
Authors: Sho Sugiura, Akira Shimizu 
Publication date: 7 November 2014
Published in: Physics, Mathematics, and All that Quantum Jazz (Search for Journal in Brave)
Abstract: We formulate statistical mechanics based on a pure quantum state, which we call a ``thermal pure quantum (TPQ) state. A single TPQ state gives not only equilibrium values of mechanical variables, such as magnetization and correlation functions, but also those of genuine thermodynamic variables and thermodynamic functions, such as entropy and free energy. Among many possible TPQ states, we discuss the canonical TPQ state, the TPQ state whose temperature is specified. % We also propose there are other TPQ states. In the TPQ formulation of statistical mechanics, thermal fluctuations are completely included in quantum-mechanical fluctuations. As a consequence, TPQ states have much larger quantum entanglement than the equilibrium density operators of the ensemble formulation. We also show that the TPQ formulation is very useful in practical computations, by applying the formulation to a frustrated two-dimensional quantum spin system.
Full work available at URL: https://arxiv.org/abs/1312.5145
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