Modeling Phase Transition and Metastable Phases

DOI10.1007/978-3-319-05591-6_87MaRDI QIDQ2946152zbMATH OpenOpenAlexFDO

Authors François James, Hélène Mathis

Publication date 16 September 2015

Published in Finite Volumes for Complex Applications VII-Elliptic, Parabolic and Hyperbolic Problems (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1402.1435

Mathematics Subject Classification ID

Liquid-gas two-phase flows, bubbly flows (76T10) Stefan problems, phase changes, etc. (80A22) Finite volume methods applied to problems in fluid mechanics (76M12)

Abstract: We propose a model that describes phase transition including metastable phases present in the van der Waals Equation of State (EoS). We introduce a dynamical system that is able to depict the mass transfer between two phases, for which equilibrium states are both metastable and stable states, including mixtures. The dynamical system is then used as a relaxation source term in a isothermal two-phase model. We use a Finite volume scheme (FV) that treats the convective part and the source term in a fractional step way. Numerical results illustrate the ability of the model to capture phase transition and metastable states.

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Cited in

(10)

• Solid-solid phase transition modelling: relaxation procedures, configurational energies and thermomechanical behaviours
• A nonisothermal thermodynamical model of liquid-vapor interaction with metastability
• Modeling nonequilibrium phase transitions and critical behavior in complex systems
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• Metastable–solid phase diagrams derived from polymorphic solidification kinetics
• Modeling of phase transitions in materials irradiated by heavy ions of high energies
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