Theory of a Quodon Gas with Application to Precipitation Kinetics in Solids Under Irradiation
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Publication:2949366
DOI10.1007/978-3-319-02057-0_14zbMATH Open1327.74062arXiv1406.4314OpenAlexW141014271MaRDI QIDQ2949366FDOQ2949366
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Publication date: 8 October 2015
Published in: Nonlinear Systems and Complexity (Search for Journal in Brave)
Abstract: Rate theory of the radiation-induced precipitation in solids is modified with account of non-equilibrium fluctuations driven by the gas of lattice solitons (a.k.a. quodons) produced by irradiation. According to quantitative estimations, a steady-state density of the quodon gas under sufficiently intense irradiation can be as high as the density of phonon gas. The quodon gas may be a powerful driver of the chemical reaction rates under irradiation, the strength of which exponentially increases with irradiation flux and may be comparable with strength of the phonon gas that exponentially increases with temperature. The modified rate theory is applied to modelling of copper precipitation in FeCu binary alloys under electron irradiation. In contrast to the classical rate theory, which disagrees strongly with experimental data on all precipitation parameters, the modified rate theory describes quite well both the evolution of precipitates and the matrix concentration of copper measured by different methods
Full work available at URL: https://arxiv.org/abs/1406.4314
Chemical and reactive effects in solid mechanics (74F25) Waves and radiation in optics and electromagnetic theory (78A40)
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