Self-assembled M₂₄L₄₈ polyhedra and their sharp structural switch upon subtle ligand variation

DOI10.1126/SCIENCE.1188605MaRDI QIDQ2962102zbMATH OpenOpenAlexWikidataFDO

Authors Qing-Fu Sun, Junji Iwasa, Daichi Ogawa, Yoshitaka Ishido, Sota Sato, Tomoji Ozeki, Yoshihisa Sei, Kentaro Yamaguchi, Makoto Fujita

Publication date 15 February 2017

Published in Science (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1126/science.1188605

zbMATH Keywords

\(M_{24}L_{48}\) coordination spheresbent ligandsbuilding blocks

Mathematics Subject Classification ID

Combinatorial properties of polytopes and polyhedra (number of faces, shortest paths, etc.) (52B05) Statistical mechanics of nanostructures and nanoparticles (82D80) Molecular structure (graph-theoretic methods, methods of differential topology, etc.) (92E10)

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(4)

• Energy landscapes for the self-assembly of supramolecular polyhedra
• The building game: from enumerative combinatorics to conformational diffusion
• Evolution of local motifs and topological proximity in self-assembled quasi-crystalline phases
• Control of connectivity and rigidity in prismatic assemblies

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