Forces and pressures in adsorbing partially directed walks

DOI10.1088/1751-8113/49/20/205001zbMATH Open1342.82067arXiv1509.07165OpenAlexW2254746915MaRDI QIDQ2991909FDOQ2991909

Authors: E. J. Janse van Rensburg, Thomas Prellberg 

Publication date: 10 August 2016

Published in: Journal of Physics A: Mathematical and Theoretical (Search for Journal in Brave)

Abstract: Polymers in confined spaces lose conformational entropy. This induces a net repulsive entropic force on the walls of the confining space. A model for this phenomenon is a lattice walk between confining walls, and in this paper a model of an adsorbing partially directed walk is used. The walk is placed in a half square lattice $L_{+}^2$ with boundary $partial{L}_{+}^2$, and confined between two vertical parallel walls, which are vertical lines in the lattice, a distance $w$ apart. The free energy of the walk is determined, as a function of $w$, for walks with endpoints in the confining walls and adsorbing in $partial{L}_{+}^2$. This gives the entropic force on the confining walls as a function of $w$. It is shown that there are zero force points in this model and the locations of these points are determined, in some cases exactly, and in other cases asymptotically.

Full work available at URL: https://arxiv.org/abs/1509.07165

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zbMATH Keywords

generating functionexact solutionentropic pressurepartially directed walkspolymer entropy

Mathematics Subject Classification ID

Random walks, random surfaces, lattice animals, etc. in equilibrium statistical mechanics (82B41) Measures of information, entropy (94A17) Exactly solvable models; Bethe ansatz (82B23) Statistical mechanics of polymers (82D60)

Cited In (7)

• Osmotic pressure of confined square lattice self-avoiding walks
• Adsorption of pulled directed paths in a slanted boundary
• A directed walk model of a long chain polymer in a slit with attractive walls
• Confining multiple polymers between sticky walls: a directed walk model of two polymers
• Self-avoiding walks in a slab: rigorous results
• The pressure exerted by adsorbing directed lattice paths and staircase polygons
• Exact solution of weighted partially directed walks crossing a square

Uses Software

• Maple

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