Transient fluctuation theorems for the currents and initial equilibrium ensembles

DOI10.1088/1742-5468/2014/10/P10033zbMATH Open1456.82836arXiv1408.5941WikidataQ59457498 ScholiaQ59457498MaRDI QIDQ3301769FDOQ3301769

Authors: Matteo Polettini, Massimiliano Esposito 

Publication date: 11 August 2020

Published in: Journal of Statistical Mechanics: Theory and Experiment (Search for Journal in Brave)

Abstract: We prove a transient fluctuation theorem for the currents for continuous-time Markov jump processes with stationary rates, generalizing an asymptotic result by Andrieux and Gaspard [J. Stat. Phys. 127, 107 (2007)] to finite times. The result is based on a graph theoretical decomposition in cycle currents and an additional set of tidal currents that characterize the transient relaxation regime. The tidal term can then be removed by a preferred choice of a suitable initial equilibrium ensemble, a result that provides the general theory for the fluctuation theorem without ensemble quantities recently addressed in [Phys. Rev. E 89, 052119 (2014)]. As an example we study the reaction network of a simple stochastic chemical engine, and finally we digress on general properties of fluctuation relations for more complex chemical reaction networks.

Full work available at URL: https://arxiv.org/abs/1408.5941

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Mathematics Subject Classification ID

Dynamic lattice systems (kinetic Ising, etc.) and systems on graphs in time-dependent statistical mechanics (82C20) Dynamics of random walks, random surfaces, lattice animals, etc. in time-dependent statistical mechanics (82C41)

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Cited In (10)

• Lag inequality for birth–death processes with time-dependent rates
• Fluctuation theorem for currents and Schnakenberg network theory
• Fluctuation relations for a few observable currents at their own beat
• Cycle/cocycle oblique projections on oriented graphs
• Fluctuation theorem for birth–death or chemical master equations with time-dependent rates
• The measure-theoretic identity underlying transient fluctuation theorems
• The transient fluctuation theorem of sample entropy production for general stochastic processes
• On the asymptotic convergence of the transient and steady-state fluctuation theorems
• A fluctuation theorem for currents and non-linear response coefficients
• Effective fluctuation and response theory

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