A generalized detailed balance relation

DOI10.1007/S10955-016-1564-2zbMATH Open1348.82070arXiv1510.08357OpenAlexW3101763119MaRDI QIDQ330613FDOQ330613

Authors: David Ruelle 

Publication date: 26 October 2016

Published in: Journal of Statistical Physics (Search for Journal in Brave)

Abstract: Given a system $M$ in a thermal bath we obtain a generalized detailed balance relation for the ratio $r=p{i}_{a}u(KoJ)/p{i}_{a}u(JoK)$ of the transition probabilities $M:JoK$ and $M:KoJ$ in time $au$. We assume an active bath, containing solute molecules in metastable states. These molecules may react with $M$ and the transition $JoK$ occurs through different channels $alpha$ involving different reactions with the bath. We find that $r=sum{p}^{a}lpha{r}^{a}lpha$, where $p^{a}lpha$ is the probability that channel $alpha$ occurs, and $r^{a}lpha$ depends on the amount of heat (more precisely enthalpy) released to the bath in channel $alpha$.

Full work available at URL: https://arxiv.org/abs/1510.08357

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zbMATH Keywords

biologystatistical mechanicsnon-equilibriumdetailed balance

Mathematics Subject Classification ID

Irreversible thermodynamics, including Onsager-Machlup theory (82C35)

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Cited In (5)

• Detailed balance and intermediate statistics
• The involution kernel and the dual potential for functions in the Walters' family
• Thermodynamic formalism on the Skorokhod space: the continuous-time Ruelle operator, entropy, pressure, entropy production and expansiveness
• On information gain, Kullback-Leibler divergence, entropy production and the involution kernel
• Representation of detailed balance by moments

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