Two-temperature continuum thermomechanics of deforming amorphous solids
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Abstract: There is an ever-growing need for predictive models for the elasto-viscoplastic deformation of solids. Our goal in this paper is to incorporate recently developed out-of-equilibrium statistical concepts into a thermodynamically consistent, finite-deformation, continuum framework for deforming amorphous solids. The basic premise is that the configurational degrees of freedom of the material --- the part of the internal energy/entropy that corresponds to mechanically stable microscopic configurations --- are characterized by a configurational temperature that might differ from that of the vibrational degrees of freedom, which equilibrate rapidly with an external heat bath. This results in an approximate internal energy decomposition into weakly interacting configurational and vibrational subsystems, which exchange energy following a Fourier-like law, leading to a thermomechanical framework permitting two well-defined temperatures. In this framework, internal variables that carry information about the state of the material equilibrate with the configurational subsystem, are explicitly associated with energy and entropy of their own, and couple to a viscoplastic flow rule. The coefficients that determine the rate of flow of entropy and heat between different internal systems are proposed to explicitly depend on the rate of irreversible deformation. As an application of this framework, we discuss two constitutive models for the response of glassy materials, a simple phenomenological model and a model related to the concept of Shear-Transformation-Zones as the basis for internal variables. The models account for several salient features of glassy deformation phenomenology. Directions for future investigation are briefly discussed.
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Cited in
(9)- Model of viscous flow of glass-forming liquids and glasses
- Discontinuous yielding transition of amorphous materials with low bulk modulus
- Plastic flow in very low temperature regime within annular micropores
- Two-subsystem thermodynamics for the mechanics of aging amorphous solids
- Metal viscoplasticity with two-temperature thermodynamics and two dislocation densities
- A thermo-mechanically coupled theory for large deformations of amorphous polymers. I: Formulation
- A constitutive model for thermoplastics based on two temperatures
- Scaling of relaxation and excess entropy in plastically deformed amorphous solids
- Parallel three-dimensional simulations of quasi-static elastoplastic solids
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