Geometrothermodynamics
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Publication:3442181
DOI10.1063/1.2409524zbMATH Open1121.80011arXivphysics/0604164OpenAlexW4249327119WikidataQ60043407 ScholiaQ60043407MaRDI QIDQ3442181FDOQ3442181
Authors: Hernando Quevedo
Publication date: 16 May 2007
Published in: Journal of Mathematical Physics (Search for Journal in Brave)
Abstract: We present the fundamentals of geometrothermodynamics, an approach to study the properties of thermodynamic systems in terms of differential geometric concepts. It is based, on the one hand, upon the well-known contact structure of the thermodynamic phase space and, on the other hand, on the metric structure of the space of thermodynamic equilibrium states. In order to make these two structures compatible we introduce a Legendre invariant set of metrics in the phase space, and demand that their pullback generates metrics on the space of equilibrium states. We show that Weinhold's metric, which was introduced {it ad hoc}, is not contained within this invariant set. We propose alternative metrics which allow us to redefine the concept of thermodynamic length in an invariant manner and to study phase transitions in terms of curvature singularities.
Full work available at URL: https://arxiv.org/abs/physics/0604164
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