Frame transformation relations and symmetry analysis of fluxional symmetric rotor dimers

DOI10.3390/SYM5010086MaRDI QIDQ350646zbMATH OpenOpenAlexFDO

Authors Horace T. Crogman, Bumgyunmiga Choi, Harrison B. Chen, William G. Harter

Publication date 9 December 2016

Published in Symmetry (Search for Journal in Brave)

Copyright license Creative Commons Attribution 4.0 International

Full work available at URL https://doi.org/10.3390/sym5010086

zbMATH Keywords

clusterdimersfluxionalframerotationspintransformation

Mathematics Subject Classification ID

Permutation groups (20B99) Finite-dimensional groups and algebras motivated by physics and their representations (81R05) Molecular physics (81V55)

Review text

Summary: The theory of Frame transformation relations between the states of Born Oppenheimer and the weak coupling approximations is developed for polyatomic molecules. The symmetry relations are a generalization of the frame transformation relations derived by Harter and Crogman for coupled rotor molecules. A key internal symmetry label (named ``soul) is defined so that it remains a constant label for frame transformation relations, and is conserved during vibronic transitions, ionization, and even dissociation provided the nuclear spin-rotation interaction is relatively small. Simplified procedures are given for obtaining selection rules, statistical weights, and matrix elements of multipole operators for common molecules having various point symmetries.

Recommendations

• scientific article; zbMATH DE number 3980102
• Partial dynamical symmetry in molecules
• Approximate symmetry characteristics using fuzzy-subset theory study for chiral transitions of allene-1,3,-dihalides
• scientific article; zbMATH DE number 1985217
• Dipole moment operator and spectral parameters of torsion transitions

Cites work

• scientific article; zbMATH DE number 3026059 (Why is no real title available?)
• scientific article; zbMATH DE number 3057922 (Why is no real title available?)
• On Quantitative Substitutional Analysis

Cited in

(3)

• Generalised Fulton-Gouterman transformation for systems of abelian symmetry
• Rotations of occupied invariant subspaces in self-consistent field calculations
• Dynamical symmetry in a minimal dimeric complex

This page was built for publication: Frame transformation relations and symmetry analysis of fluxional symmetric rotor dimers

Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q350646)