Dielectric screening in a spherical cavity

DOI10.1088/1751-8113/41/37/375402MaRDI QIDQ3528215zbMATH OpenOpenAlexFDO

Authors Christopher J. Glosser, Roger C. Hill

Publication date 8 October 2008

Published in Journal of Physics A: Mathematical and Theoretical (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/0807.1553

Mathematics Subject Classification ID

Molecular physics (81V55)

Abstract: In this work we examine the electrostatic screening potential due to a point charge located off-centre in a spherical dielectric cavity. This potential is expanded for the case in which the dielectric constant $epsilon$ is large, several methods of finding the terms in the expansion are investigated, and closed-form expressions are found through third order in $epsilon$ along with error bounds. Finally, possible uses of these expressions in molecular dynamics simulations of isolated charged molecules is discussed.

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Cited in

(4)

• Dielectric screening effects in molten AgI–AgBr system
• Phenomenological models of dielectric functions and screened Coulomb potential
• Spherical harmonic expansion of short-range screened Coulomb interactions
• Interaction potential for a system of \(N\) charged particles near a spherical interface

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